CSIR UGC JRF NET Chemistry Question Paper

CSIR UGC JRF NET Chemistry Question Paper
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Showing posts with label MCQ on Chemical bonding. Show all posts
Showing posts with label MCQ on Chemical bonding. Show all posts

Chemical Bonding Multiple Choice with answer key

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You may use a periodic table and a calculator to do this test. 
 

Multiple-choice section

Please write the letter of the most correct answer in the space next to the problem for each of the following ten problems:

1)         How many valence electrons does gallium have?
            a)         1                                             c)         5
            b)        3                                             d)        13

2)         How many electrons does phosphorus have to gain in order to achieve a noble-gas electron configuration?
            a)         2                                             c)         5
            b)        3                                             d)        4

3)         How many valence electrons are transferred from the nitrogen atom to each potassium in the formation of the compound potassium nitride?
            a)         0                                             c)         3
            b)        1                                             d)        5

4)         Which of the following takes place in an ionic bond?
            a)         Two atoms share two electrons
            b)        Two atoms share electrons such that both follow the octet rule.
            c)         Like-charged ions attract
            d)        Oppositely-charged ions attract

5)         What is the net charge of the ionic compound calcium fluoride?
            a)         -2                                            c)         +2
            b)        0                                             d)        -1

6)         Ionic compounds are normally found in what state at room temperature?
            a)         solid                                       c)         gas
            b)        liquid                                      d)        none of these

7)         The melting temperature of potassium chloride is relatively…
            a)         low                                         c)         KCl does not melt
            b)        high                                        d)        about room temperature

8)         What does the term “coordination number” refer to?
            a)         The number of oppositely charged ions surrounding a particular ion
            b)        The number of atoms in a unit cell
            c)         The number of valence electrons in an atom
            d)        The number of times a compound forms covalent bonds

9)         What characteristic of metals makes them good electrical conductors?
            a)         Mobile valence electrons
            b)        Mobile protons
            c)         Their crystal structures rearrange easily
            d)        Mobile cations

10)       How many electrons are shared between two atoms in a double covalent bond?
            a)         8                                             c)         4
            b)        6                                             d)        2

11)       How many unshared pairs of electrons are there in hydrogen iodide?
            a)         1                                             c)         3
            b)        6                                             d)        none of these

12)       Which of the following elements occurs naturally as a diatomic molecule with three covalent bonds?
            a)         oxygen                                               c)         fluorine
            b)        hydrogen                                d)        nitrogen

13)       When one atom contributes both bonding electrons in a single covalent bond, the bond is called a(n)…
               a)      ionic covalent bond
            b)        polar covalent bond
            c)         one-sided covalent bond
            d)        coordinate covalent bond


14)       Which of the following pairs of elements can be joined by a covalent bond?
            a)         Li and Br                                c)         Mg and C
            b)        N and C                                               d)      He and O

15)       In which of the following compounds/ions is there an exception to the octet rule?
            a)         SF6                                         c)         MgO
            b)        PH3                                         d)        BH4+1




 
Answer Key:

1)         b – Valence electrons are the number of s- and p-electrons since the last noble gas.  The d-electrons don’t count.

2)         b – It has five valence electrons, and wants eight like argon.

3)         a – Electrons are transferred from K to N, not the other way around.

4)         d

5)         b – Ionic compounds have no overall charge, because the cations and anions cancel each other out.

6)         a – Ionic compounds generally have high melting and boiling points because the positive and negative charges are tightly bound to one another.

7)         b – See explanation above

8)         a

9)         a – If this doesn’t make sense, study the “electron sea theory” of metallic bonding.

10)       c – Because each bond contains two electrons, a double bond will contain 4 electrons.

11)       c – All three unshared electron pairs are on the iodine atom.

12)       d – The others are all naturally diatomic, but only N2 has triple bonds.

13)       d

14)       b – The differences in electronegativity between the other elements are too large for covalent bonding to occur.

15)       a – Sulfur has six electron pairs around it.

Chemistry - Fill in the Blanks model Questions Chemical Bonding

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1. There are ____________________ π (pi) bonds in a nitrogen molecule. (JEE 1982)
Anwer : 2

2. __________ hybrid orbitals of nitrogen are involved in the formation of ammonium ion. (JEE 1982)

Answer sp³

3. The terminal carbon atom in butane is _____________ hybridized. (JEE 1985)

Answer sp³

The shape of [CH3] + is ------------------------.
(JEE 1990)
Answer: Triangular planar

4.The valence atomic orbitals of carbon in silver acetylide is _________________.
(JEE 1990)


Answer: sp

5.IN P4O10, the number of oxygen atoms bonded to each phosphorus atom is ____________ .
(JEE 1992)


Answer: 4

6.When N2 goes to N2+
The N—N bond distance _________ and when O2 goes to )2+, the O—O bond distance ______________.


(JEE 1996)
Answer: increases, decreases

True or False type question chemistry - Chemical Bonding

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1. Linear overlap of two atomic p-orbitals leads to a sigma bond. (JEE 1983)

True

2. The H-N-H bond angle in NH3 is greater than the H-As-H bond angle in AsH3.

True

Reason: Repulsion is more in NH3 which makes the bond angle greater than in AsH3.

3. All molecules with polar bonds have dipole moment. (JEE 1985)


False.

Reason; If symmetrical arrangement of atoms is there, there is no dipole moment. Example CCl4.

4. SnCl2 is nonlinear molecule. (JEE 1985)
True

There is a lone pair in the bond. Due to repulsion between Lone pair and bonding pair, the bond angle less than 180°.

5. sp² hybrid orbitals have equal s and p character.

False

sp² hybrid use one s orbital and 2 p orbital for hydridisation. Hence sp² hybrid orbitals have 1/3 s character and 2/3 p character.

6. All the Al-Cl bonds in Al2Cl6 are equivalent. (JEE 1989)

False

The terminal Al-Cl bonds are different from the bridge Al-Cl bonds.

7. Nitric oxide, though an odd electron molecule, is diamagnetic in liquid state. (JEE 1991)

False

In liquid state, some dimerization takes place, but it is only partial. So it is still paramagnetic only.

8. Dipole moment of CH3F is greater than CH3Cl. (JEE 1993)
False

Bond distance is more in CH3Cl and hence more dipole moment.
Dipole moment = charge * distance

Chemistry Past year IIT JEE question bank - Chemical Bonding

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1. The ion that isoelectronic with CO is

a. CN-
b. O2+
c. O2-
d. N2+
(JEE 1982)

ans: (a)

isoelectronic means same number of electrons

2. carbon tetrachloride has no net dipole moment because of

a. its planar structure
b. its regular tetrahedral structure
c. similar sizes of carbon and chlorine atoms
d. similar electron affinities of carbon and chlorine
(JEE 1983)

ans (b)

3. which one among the following does not have the hydrogen bond?

a. phenol
b. liquid NH3
c. water
d. liquid HCl
(JEE 1983)

Ans: (d)

4. the types of bonds present in CuSO4.5H2O are only

a. electrovalent and covalent
b. electrovalent and coordinate covalent
c. electrovalent, covalent and coordinate covalent
d. covalent and coordinate covalent

5. On hybridization of one s and one p orbitals we get:

a.two mutually perpendicular orbitals
b. two orbital at 180°
c. four orbitals directed tetrahedrally
d. three orbital in a plane
(JEE 1984)

Answer: (b)

6. the molecule having one unpaired electron is:

a. NO
b. CO
c. CN-
d. O2
(JEE 1985)

Ans: (a)

7. The bond between two identical non-metal atoms has a pair of electrons:


a. unequally shared between the two.
b.transferred fully from one atom to another
c. with identical spins
d. equally shared between them
(JEE 1986)

Ans: (d)

8. the hydrogen bond is strongest in:
a. O-H…S
b. S-H…O
c. F-H…S
d. F-H...O
(JEE 1986)

Answer: ( c )

9. The hybridization of sulphur dioxide is:

a. sp
b. sp²
c. dsp²
d. sp³
(JEE 1986)

answer (b)

10. The bonds present in N2O5 are ______

a. only ionic
b. covalent and coordinate
c. only covalent
d. covalent and ionic
(JEE 1986)

ans: (b)

Chemistry: Multiple Choice Questions in Chemical bonding

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Chemistry: Multiple Choice Questions in Chemical bonding
1. Which substance has a polar covalent bond between its atoms?
(A) K3N
(B) Ca3N2
(C) NaCl
(D) F2
(E) NH3

2. Which kinds of bonding can be found in a sample of H2O(l)?

(A) Hydrogen bonds only
(B) Nonpolar covalent bonds only
(C) Ionic and nonpolar hydrogen bonds
(D) Both polar covalent and hydrogen bonds
(E) Metallic and ionic bonds

3. When an ionic compound is dissolved in water, the ions in solution can best be described as
(A) hydrated molecules only
(B) dehydrated ions and molecules
(C) both hydrated molecules and hydrated ions
(D) neither hydrated ions nor hydrated molecules
(E) hydrated ions only

4. Which substance represents a molecule that can combine with a proton (H1+)?
(A) NH3
(B) Na1+
(C) HCl
(D) H3O1+
(E) H

5. Which compound contains no ionic character?
(A) NH4Cl
(B) CaO
(C) K2O
(D) Li2O
(E) CO

6. The forces of attraction that exist between nonpolar molecules are called
(A) Van der Waals / dispersion forces
(B) ionic bonds
(C) covalent bonds
(D) electrovalent bonds
(E) metallic bonds

7. Which substance is a network solid?

(A) Li2O
(B) SiO2
(C) H2O
(D) CO2
(E) NaCl

8. Which molecule is a polar molecule?
(A) N2
(B) H2O
(C) CH4
(D) CO2
(E) KCl

9. Which is the chemical formula for iron(III)sulfate?
(A) Fe2SO4
(B) Fe3SO4
(C) Fe(SO4)3
(D) Fe2(SO4)3
(E) Fe2S3

10. In which of the following compounds are hydrogen bonds between molecules the strongest?
(A) HF
(B) HCl
(C) HBr
(D) HI
(E) HAt

Answer
1. (E) 2. (D) 3. (E)4. (A) 5. (E) 6. (A)7. (B) 8. (B) 9. (D) 10. (A)

Chemistry: Objective type question on Chemical Reaction

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Find the correct answer by clicking on the choice given.
1. Which of the following chemical equations correctly represents the reaction between calcium hydroxide and hydrochloric acid?




2. In the following reaction, the element that is oxidized is _?_ and the element that is the oxidizing agent is _?_.

(a) zinc...zinc

(b) bromine...bromine

(c) zinc...bromine

(d) bromine...zinc



3. Which of the following chemical equations correctly represents the reaction between sodium carbonate and phosphoric acid?




4. Which of the following compounds is the strongest Brønsted acid?

(a) HCl

(b) HBr

(c) H2O

(d) H2S
5. Potassium bromate, KBrO3, is an additive to some flour (brominated flour) used to improve texture in the dough. It is a suspected carcinogen and some consumer groups want to ban this additive. The industry says that this compound is decomposed to KBr and O2 when the bread is baked and is thus not a risk to the health of the consumer...hmmm. When this reaction is balanced, the sum of the coefficients for the KBrO3 and KBr and O2 will be... Can you think of an easy experiment to test the response made by industry?...answer (d).

(a) 3.5

(b) 5

(c) 7

(d) experiment



6. An iron nail was immersed in a solution of copper sulfate and when it was removed from the solution, it was coated with a layer of copper metal. After a different iron nail was immersed in a solution of zinc nitrate and removed, this nail rusted just as rapidly as a new iron nail. Rank these three metals in order of activity from most active to least active.

(a) Zn > Cu > Fe

(b) Fe > Cu > Zn

(c) Zn > Fe > Cu

(d) Cu > Fe > Zn



7. What is the balanced net ionic equation for the reaction of CaCl2 and AgNO3?



8. The "conjugate acid" in the reaction of H2SO4 with NaOH is...

(a) H2SO4

(b) NaOH

(c) Na2SO4

(d) H2O